SummaryStudies were initiated at the Hanford Site to evaluate the process controlling the transport of fluids in the vadose zone and to develop a reliable database for testing vadose-zone transport models. These models are needed to evaluate contaminant migration through the vadose zone to underlying groundwater at Hanford. A study site that had previously been extensively characterized using geophysical monitoring techniques was selected in the 200 E Area. Techniques used previously included neutron probe for water content, spectral gamma logging for radionuclide tracers, and gamma scattering for wet bulk density. Building on the characterization efforts of the past 20 years, the site was instrumented to facilitate the comparison of nine vadose-zone characterization methods: advanced tensiometers, neutron probe, electrical resistance tomography (ERT), high-resolution resistivity (HRR), electromagnetic induction imaging (EMI), cross-borehole radar (XBR), and cross-borehole seismic (XBS). Soil coring was used to obtain soil samples for analyzing ionic and isotopic tracers.Laboratory-scale experiments with hypersaline fluids in Hanford sediments suggest that fluid properties may influence transport behavior, to the extent of finger formation, through an interaction between fluid and hydraulic properties. Yet, the importance of these mechanisms to field-scale transport is largely unknown, thereby limiting the accuracy of contaminant-transport predictions. To assess the importance of these interactions in field-scale solute transport, tank leaks were simulated by performing a series of injections with dilute fluids in late spring and early summer of FY 2000 and with hypersaline fluids (36 wt% sodium thiosulfate) during the spring of 2001. In both tests, a suite of isotopic and ionic tracers was included in the injected fluids. The test in FY 2000 consisted of injecting to ground a series of five 3875 L (1000 gal) pulses of water and tracers, weekly, for five weeks. The FY 2001 test, which was designed partly to evaluate the effects of fluid properties and transport processes, involved the injection of 19,000 L (5000 gal) of hypersaline fluid over the course of 5 weeks. This was followed by 11,400 L (3000 gal) of solute-free water applied in a 2-week period. In FY 2000, infiltration and redistribution were monitored using the nine characterization methods over the course of the injections and for 2 months after the last injection. In FY 2001, all methods except EMI were used to monitor the infiltration and redistribution of the 30,000 L (7925 gal) plume over the course of 3 months.Thus far, field-measured distributions of soil water content have been analyzed using threedimensional spatial-moment analysis. Results clearly show that the subsurface distributions of both the dilute and hypersaline fluids are controlled by an interaction between small-scale horizontal stratification and fluid properties. The centers of mass for the two plumes were similar in the lateral and transverse directions, but were significantly d...