Lead citrate is a key precursor for the green recycling of spent lead acid battery paste in a citric acid/sodium citrate (CA/SC) solution. In this study, the main paste component, PbSO 4 , was leached and crystallized to yield lead citrate. Results showed that the leaching of PbSO 4 in citric acid/sodium citrate solution was remarkably enhanced by an increase in temperature from 35 • C to 95 • C and an increase in sodium citrate (SC) concentration from 50 to 650 g/L. In comparison, increasing the citric acid/sodium citrate molar ratio inhibited this leaching. Controlled crystallization through cooling the solution or adjusting the pH of the solution can effectively produce lead citrate crystals. The X-ray diffraction patterns of four products obtained in a comparison test were all consistent with Pb 3 (C 6 H 5 O 7 ) 2 . However, the scanning electron microscopy analysis suggested that the morphology was distinct from rods to sheets, which were mainly affected by the temperature variation.