Religious assistance is an effective tool in helping the victims of violence, but so far, it has not been investigated that what promotes the persons aggrieved in the workplace to seek such assistance. Therefore, this study aimed to identify the motives of persons who have experienced destructive relationships, which inspire the search for spiritual assistance in religious organizations, seeking to develop the provision of such service. After the analysis of the scientific literature, a questionnaire “Motives of Persons Aggrieved at Work for Seeking Spiritual Assistance (MP-SSA-40)” was developed and validated. In this study, a survey was conducted on 463 persons working in Lithuanian organizations using the questionnaire survey method. The correlation and regression analyses were performed. The study has shown that the religiosity of the victim is not the only condition for seeking spiritual assistance. Significant factors are the congruence of values borne by the person and the religious organization, the motives arising from the relation with the person providing assistance, and the motives determined by circumstances that create an important contextual background. The established trends show that by solving work-related problems and problems of interpersonal relationships of assistance providers, obstacles hindering the implementation of intrinsic motives of the victim to apply for spiritual assistance to the religious organization, providing it can be removed. The value of the article is demonstrated by the fact that it fills the existing gaps of knowledge about the motives of victims of destructive relationships at work, seeking religious spiritual assistance. In addition, a new and reliable instrument to measure such motives is proposed.