We present a dispersive method which allows to investigate the low-energy couplings of chiral perturbation theory at the next-to-leading order (NLO) in the 1/N C expansion, keeping full control of their renormalization scale dependence. Using the resonance chiral theory Lagrangian, we perform a NLO calculation of the scalar and pseudoscalar twopoint functions, within the single-resonance approximation. Imposing the correct QCD short-distance constraints, one determines their difference Π(t) ≡ Π S (t) − Π P (t) in terms of the pion decay constant and resonance masses. Its low momentum expansion fixes then the low-energy chiral couplings L 8 and C 38 . At µ 0 = 0.77 GeV, we obtain L r 8 (µ 0 ) SU (3) = (0.6 ± 0.4) · 10 −3 and C r 38 (µ 0 ) SU (3) = (2 ± 6) · 10 −6 .