“…Polycrystalline coatings and materials have shown great functional and structural potential and outstanding mechanical and physical properties [1]. Alloys, metals, and ceramics with a polycrystalline microstructure are widely used in engineering applications, including but not limited to electronic devices [2], manufacturing [3], solar and fuel cells [4,5], structural materials [6], thin-film transistors [7], future fusion applications [8], scintillators [9], laser media [10], and light-emitting diodes [11]. Hence, it is important for both practical and phenomenological reasons to know and predict the kinetics and mass transport mechanisms in polycrystalline coatings.…”