The Many Facets of RuII(dppe)2 Acetylide Compounds
Stéphane Rigaut,
Olivier Galangau
Abstract:In this contribution, we describe the various research domains in which RuII alkynyl derivatives are involved. Their peculiar molecular properties stem from a strong and intimate overlap between the metal centered d orbitals and the p system of the acetylide ligands, resulting in plethora of fascinating properties such as strong and tunable visible light absorption with a strong MLCT character essential for sensing, photovoltaics, light‐harvesting applications or non‐linear optical properties. Likewise, the d… Show more
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