Geothermal energy is a renewable energy that is environmentally friendly and will help reduce greenhouse emission resulting from the burning of fossil fuels. Nigeria has numerous geothermal surface manifestations like hot and warm springs in most parts of the country that has not been exploited or explored due to the initial high cost of exploration. Most research conducted on geothermal energy prospects in Nigeria considered specific geographical sections. Due to the geological features of Nigeria, the direct and indirect tectonic activities, there is the need to map the thermal anomalies over Nigeria to determine likely geothermal wells and ground heat catchment in Nigeria. Forty years remote sensing dataset (1980–2019), was obtained from the MERRA-2 for three hundred and two (302) locations across Nigeria. The acquired thermal parameters were processed using known models. The data was also analyzed statistically and spatially using the Statistical Package for Social Sciences (SPSS) and Quantum Geographic Information System (QGIS). The results of show that the Gummel-Kumaganum areas of chad basin, Owode-igbo ora areas of the Dahomey basin, Belli area of the basement complex in Taraba state, potiskum areas of the Upper benue Basin, Ekpoma-kwale, itu areas of the Niger delta basin are middle geothermal wells with the terrestial radiation of < −702 W/m2 while the terrestial radiation >200 W/m2 in the Gummi area of the sokoto basin, Hunkuyi area of the basement complex in the northeast, Gashua area of the chad basin, Ozubulu-idah area of Anambra basin, Atijere area of the Dahomey basin, Agbasa, Omoko, Akamkpa area of Niger delta basin, Shaki area of the southwest basement complex are heat catchment regions. Other heat catchment areas had been identified for standalone energy generation. Also, the thermal anomalies in those areas were significant. The validation of the result was achieved via benchmarking similar geothermal well around the globe and ground truthing at Ijebu-Ode Nigeria. Based on the thermal reversal depth (TRD) concept, Ijebu-Ode may have a deep geothermal well with temperatures pattern similar to geothermal wells in other parts of the globe. It is recommended that ground measurement should be carried out in the basement complex to cater for geothermal systems whose mechanism is based on conduction.