“…In this sense, the strong self-assembly tendency of 4a to form interconnected networks from cast solutions has mediated the system to the entropically favoured formation of extended collinear networks of interconnected carbon nanotubes over larger areas and volumes. This spatially aligned higher-level superstructure is facilitated by the considerable shape anisotropy of the nanotubes and the rods/rings in the molecular network, thus resulting in entropy-driven directional ordering 43,48 . Although this is not the first case of circularly arranged nanostructures (for example, nanoparticles 41,[49][50][51] , nanorods, 52 , nanowires 53 , carbon nanotubes 54,55 ), it represents to our knowledge the first example where self-assembled structures can efficiently address the orientation and interconnection of carbon nanotubes, both in circular structures and in long-range networks, and in a solid polymer matrix.…”