“…Linear response theory is widely used for determining the stopping power, and it is of interest to examine this approximate description in the light of our first-principles dynamics result. The observed shift in the Bragg peak velocity among different projectile ions is beyond the description based on linear response (LR) theory, which can be expressed as S ( v ) = 4 π Z 2 v 2 L ( v ) where S ( v ) is the electronic stopping power, v is the projectile ion velocity, and L ( v ) is the velocity-dependent term known as the stopping logarithm. , There exist a number of different expressions for the stopping logarithm, , which incorporates information on the target material only. Generally, in LR theory, the charge of the projectile ion is treated as a velocity-independent quantity and ions are assumed to be fully ionized. , This assumption leads to well-known issues such as incorrectly predicting the same Bragg peak position for all ions. ,, Instead, the ion charge can be treated as a function of the ion velocity, Z ( v ), being equal to the mean charge for each ion in liquid water for this study.…”