Unlike the compounds of the natural air atmosphere, the
lightning
systems are primarily focused on NO(X2Π), NO2(12A′), and O(3P) concentrations
that occurred newly and highly in the ground electronic structure.
While the NO/NO2 concentrations ratio is about 2000 during
the lightning flash, this ratio becomes about 0.8 right after the
lightning flash. The reason for this decrease in the ratio is the
disappearance of the high temperature that prevents the formation
of NO2 (with the combination of NO and O) and of the photon
energy that causes its dissociation (NO2 + hv → NO + O) right after the lightning flash. However, this
study will focus on the reactions that contribute to the NO concentration,
except for the combination of N and O atoms during lightning flash.
To do this, it was focused on the reactive scattering states (especially
the NO-exchange) of the NO + O collision and the photo-dissociation
of NO2, which provide the formation of the NO molecule
in the ground electronic state. This case raises important questions.
To what extent do the NO-exchange reaction and the photo-dissociation
of NO2 contribute to the atmospherically observed NO molecules?
or how can the vibrational quantum states of the NO molecules formed
by the photo-dissociation be effected on the NO + O1 collision
to produce a NO1 molecule? These conditions may contribute
to the concentrations of NO high during lightning flashes. Under low
collision energy (between 0.1 and 0.3 eV), the NO (v = 0) population dissociated by a photon can act as reactants in
the NO-exchange reactive scattering on the doublet electronic state.
Since it is assumed that all of the NO2 molecules are due
to NO in the lightning flash system, this is one of the reasons that
makes the NO population so high during lightning flash. Therefore,
in the light of considering that the lightning system supports the
formation of highly vibrating molecular groups, it might also support
the formation of O2 molecules. In particular, it was shown
that the v = 4 quantum state of the NO molecule over
the doublet state between collision energies of 0.9–1.5 eV
and the v = 5 quantum state of the NO molecule over
the quartet state between collision energies of 1.0–1.5 eV
contribute to O2 formation.