The Mechanism of Magnetically Tuned Singlet–Triplet Avoided Crossings in the Ã1A2–X̃1A1 410 Band of Thioformaldehyde H2CS

Optical-IR double resonance effect for the rovibronic state of (COF)2

“…The OIRDR spectrum was recorded for the 4 31 3 21 , ð e A 1 A u Þ0 0 0 line (Ar þ 1.2% (COF) 2 mixture) using an IR field power of W IR ¼ 10 W ( IR % 990:1 cm À1 ; exc % 32 446:3 cm À1 ), 30 G min À1 scanning rate and a skimmer inlet diameter of 2 mm. The recorded OIRDR spectrum is shown in figure 1.…”

“…Time-resolved experiments were run for the OIRDR spectral line located at about 3134 G. We also studied the influence of NO on the OIRDR spectrum and fluorescence decay. Analysis and discussion of the experimental data were carried out using the previously proposed theory [10,[21][22][23].…”