The mechanism of the polymerization of vinyl chloride under the action of the catalytic system Ti(OC4H9)4Al(iso-C4H9)2Cl

Budanova, G.P.; Mazurek, V.V.

doi:10.1016/0032-3950(67)90371-1

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1970

1981

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Cited by 7 publications

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Polymerization of vinyl chloride and copolymerization with propylene by a ternary catalyst system

Akimoto

Yoshida

1972

J. Polym. Sci. A‐1 Polym. Chem.

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synopsisPolymerization of vinyl chloride by the ternary catalyst system of VOCbALR,Cb-ncomplexing agent waa investigated. It was suggwted that the formation of a polar complex (or chargedmnsfer complex) between AlRnCb-n and the complexing agent participated in the polymerization of vinyl chloride. In the copolymerization of vinyl chloride with propylene with the present catalyst system, it waa more diflicult to incorporate the propylene unit in the copolymer than with a typical radical catalyst.

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