2018
DOI: 10.1002/ange.201709799
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The Mesomeric Effect of Thiazolium on non‐Kekulé Diradicals in Pichia stipitis Transketolase

Abstract: It is theoretically plausible that thiazolium mesomerizes to congeners other than carbene in al ow effective dielectric binding site;e specially given the energetics and uneven electronegativity of carbene groups.H owever,s uch aphenomenon has never been reported. Nine crystal structures of transketolase obtained from Pichia stipitis (TKps) are reported with subatomic resolution, where thiazolium displays an extraordinary ring-bending effect. The bent thiazolium congeners correlate with non-KekulØ diradicals b… Show more

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