In 0.1 mass% carbon steels with phosphorus contents ranging from 0.01 to 0.2 mass%, slabs were continuously cast to a thickness of 100 mm with a laboratory scale caster. Their macro-and micro-structures were characterized, focusing on the effects of phosphorus addition on the structural evolution during solidification and subsequent cooling. Cast slabs of high phosphorus steels have a fine columnar-g-grain structure. The mean width of the columnar grain was approximately half of that in the cast slabs without the phosphorus addition. Dispersed globular a grains were observed in the a grain structure of high phosphorus steels. The globular grains evolved at the phosphorus-rich spots in the prior-g grain. The micro-segregation of phosphorus results in these structural evolutions. Since the phosphorus enrichment stabilizes bcc (d or a) phase locally at the inter-dendritic region, the phosphorus-rich spot makes d phase retained to lower temperature for the d/g transformation, and provides a predominant site for the g/a transformation. In the high phosphorus casts, therefore, the dispersed d phase are thought to pin the g grain growth more effectively in the dϩg region when the completion of the d/g transformation is remarkably suppressed by the phosphorus segregation.