Abstract. Column ozone variability has important implications for
surface photochemistry and the climate. Ice-core nitrate isotopes are suspected
to be influenced by column ozone variability and δ15N(NO3-) has been sought to serve as a proxy of column
ozone variability. In this study, we examined the ability of ice-core
nitrate isotopes to reflect column ozone variability by measuring δ15N(NO3-) and Δ17O(NO3-) in a shallow
ice core drilled at the South Pole. The ice core covers the period 1944–2005, and during this period δ15N(NO3-) showed
large annual variability ((59.2 ± 29.3) ‰ ), but
with no apparent response to the Antarctic ozone hole. Utilizing a snow
photochemical model, we estimated 6.9 ‰ additional
enrichments in δ15N(NO3-) could be caused by the
development of the ozone hole. Nevertheless, this enrichment is small and
masked by the effects of the snow accumulation rate at the South Pole over the same period of the ozone hole. The Δ17O(NO3-) record
has displayed a decreasing trend by ∼ 3.4 ‰
since 1976. This magnitude of change cannot be caused by enhanced
post-depositional processing related to the ozone hole. Instead, the Δ17O(NO3-) decrease was more likely due to the proposed
decreases in the O3 / HOx ratio in the extratropical Southern
Hemisphere. Our results suggest ice-core δ15N(NO3-)
is more sensitive to snow accumulation rate than to column ozone, but at
sites with a relatively constant snow accumulation rate, information of column ozone variability embedded in δ15N(NO3-) should be
retrievable.