1988
DOI: 10.1007/bf02645467
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The microstructure and phase relationships in rapidly solidified type 304 stainless steel powders

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Cited by 30 publications
(17 citation statements)
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“…In consequence, the reachable undercoolings with respect to the melting point are sufficient to quench in the metastable ferrite present in the fine powders, favoured by its lower surface energy in the surrounding liquid [24]. In contrast, the solidification of bigger droplets is not triggered by such high undercoolings, and thus should result in the nucleation of the equilibrium fcc structure [24,25]. The powder particles are exposed to strong shock pressures during cold spraying or explosive compaction, leading to the transformation of metastable bcc structures to austenite having a higher density.…”
Section: Discussionmentioning
confidence: 99%
“…In consequence, the reachable undercoolings with respect to the melting point are sufficient to quench in the metastable ferrite present in the fine powders, favoured by its lower surface energy in the surrounding liquid [24]. In contrast, the solidification of bigger droplets is not triggered by such high undercoolings, and thus should result in the nucleation of the equilibrium fcc structure [24,25]. The powder particles are exposed to strong shock pressures during cold spraying or explosive compaction, leading to the transformation of metastable bcc structures to austenite having a higher density.…”
Section: Discussionmentioning
confidence: 99%
“…[1][2][3][4][5][6] However, the solidification behavior of austenitic stainless steels is complicated because of the occurrence of a variety of ferrite morphologies during the solidification and subsequent solid-state transformation. Interpretation of the formation mechanism of the different ferrite morphologies is difficult due to the nonequilibrium solidification conditions and the subsequent solid-state transformation on cooling.…”
Section: Introductionmentioning
confidence: 99%
“…As a result of the increase in the chromium content in the liquid, the bcc phase was stabilized, while the depletion in chromium within the dendrite stabitemperature increased, for powder particle sizes of 30 to 45 lized the fcc phase. This type of solidification behavior was m. Figure 8 shows the fraction of fcc as a function of also reported by Wright et al [6] The martensite which is temperature for different particle sizes. The volume fraction found within the dendrite arms (Figure 3) is the result of was calculated using the ratio of the integrated intensities transformation of the fcc phase into martensite.…”
Section: A X-ray Diffraction Of the Powder Particles At Room Temperamentioning
confidence: 74%
“…Small droplets have, therefore, the lowest probability of nucleation, while larger particles have the highest probability of nucleation. [2,6,7,[18][19][20] Consequently, in the small particle sizes, the liquid is undercooled to a low temperature before the initia- [15] (open triangle) cooling rate calculated bcc for small particle sizes was earlier shown to be nucleation according to Ṫ ϭ 6h(T melt Ϫ T gas )/C L P d; and (filled line) as calculated by the numerical model. [15] controlled.…”
Section: A X-ray Diffraction Of the Powder Particles At Room Temperamentioning
confidence: 99%
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