The microwave spectrum of HGeCl

Lin, Wei; Kang, Lu; Novick, Stewart E.

doi:10.1016/j.jms.2004.11.003

Cited by 15 publications

(13 citation statements)

References 18 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The usual approximation 12,14,16 is to set the off-diagonal orbital angular momentum matrix elements equal to 1, which implies that the ratio of the hyperfine spin-rotation constants should be the same as the ratio of the rotational constants. Substituting in the numbers from The last two values should be equal if the matrix elements are the same.…”

Section: B the Bromine Spin-rotation Tensormentioning

confidence: 99%

See 1 more Smart Citation

Fourier transform microwave spectroscopy of monobromogermylene (HGeBr and DGeBr), a heavy atom carbene analog

Kang

Sunahori

Minei

et al. 2009

The Journal of Chemical Physics

Self Cite

View full text Add to dashboard Cite

Eight isotopologues of HGeBr and nine of DGeBr have been studied in natural abundance by pulsed-jet Fourier transform microwave spectroscopy. The reactive germylene species were produced in an electric discharge at the exit of a pulsed molecular beam valve using precursor mixtures of H(3)GeBr or D(3)GeBr in high pressure neon. In the 5-25 GHz operating range of the spectrometer, only a-type transitions were observed; K = 0 transitions for HGeBr and K = 0 and 1 transitions for DGeBr. From the observed transitions, an improved molecular geometry has been determined and nuclear quadruple constants for Ge and Br have been determined. The Townes-Dailey model has been extended to obtain the electron densities of the 4p orbitals on the germanium and bromine atoms from the quadruple coupling constants. These results are discussed in terms of qualitative molecular orbital theory.

show abstract

Section: B the Bromine Spin-rotation Tensormentioning

confidence: 99%

“…15 The only microwave measurements on the germylenes that we are aware of is our recent study of nine isotopologues of HGeCl by FTMW spectroscopy. 16 In the present work, we report an extensive study of the FTMW spectrum of the monobromogermylene ͑HGeBr͒ species.…”

Section: Introductionmentioning

confidence: 99%

Fourier transform microwave spectroscopy of monobromogermylene (HGeBr and DGeBr), a heavy atom carbene analog

Kang

Sunahori

Minei

et al. 2009

The Journal of Chemical Physics

Self Cite

View full text Add to dashboard Cite

show abstract

“…The spectrum of the argon trifluoroacetonitrile van der Waals complex was measured using a pulsed-jet Fourier transform microwave spectrometer which has been described elsewhere [21,22]. The spectrum was measured in the frequency range 7-15 GHz.…”

Section: Methodsmentioning

confidence: 99%

The microwave spectrum and structure of the argon trifluoroacetonitrile complex

Lin

Novick

2007

Journal of Molecular Spectroscopy

Self Cite

View full text Add to dashboard Cite

“…There is an excellent recent review of the design parameters of FTMW spectrometers by Grabow, et al [4]. The details of our version of the spectrometer are given elsewhere [5,6]. A mixture of 0.5% cyanoacetylene, 0.5% phosphine, and 99% neon was expanded through a 0.8 mm diameter General Valve nozzle followed by a 900 V pulsed discharge immediately upstream of the nozzle.…”

Section: Methodsmentioning

confidence: 99%