The Pounamu Ultramafic Belt (PUB), part of the Alpine Schists, comprises a metamorphosed ophiolitic sequence overlain by a thin pelagic unit, a massive quartzofeldspathic biotite rock and quartzofeldspathic turbidites derived from a Torlesse/Otago Schist source. Constituent zircon populations from the biotite rock are euhedral/prismatic and are unabraded. One sample is near unimodal, with a UÁPb SHRIMP age of 106.691.4 Ma (2s m ), while the other has two peaks at 108.091.6 Ma and 71.991.8 Ma. The older age is interpreted to represent the age of igneous activity and sedimentation, while the younger peak is interpreted to represent the age of subsequent metamorphism. The whole-rock geochemistry of the biotite rock, its field distribution and zircon morphology are consistent with an origin by eruption of a dacitic air-fall tuff. The base of the Pounamu sequence divides predominantly psammitic Triassic metasediments to the east from intensely deformed, but regionally west-facing, Cretaceous metasediments to the west. These Cretaceous metasediments have undergone multiphase deformation and metamorphism by 72 Ma, a timing that contrasts markedly with previous interpretations for Jurassic amalgamation of the Haast Schists.