“…6 For example, in the case of the Anderson−Evans POM, which is formed by a plane of seven edge-sharing Mo-oxo octahedra (Figure 1a) and the central M site, within a ring of six MoO 6 octahedra, can be substituted by other transition metals, including Fe, Co, Ni, Cu, Rh, and Pt, to enable different catalytic reactions. 7−9 Recent efforts toward POM-based catalysis have dispersed them on high surface area supports, 10,11 such as porous silica and metal−organic frameworks (MOFs), 12,13 to enhance accessibility to the POM relative to the bulk. Here, the versatile tunability of MOF pore geometries and chemical environments 14 Zr.HVCDAMXLLUJLQZ.MOFkey-v1.csq) can exhibit higher catalytic reactivity than either component alone.…”