The thesis applies solutions to boundary value problems of a class of fractional differential equation coupled systems with a p-Laplacian operator. This article applies this part of the content to alleviate the psychological barriers of college students. This article transforms the tendency of individual consciousness in college students’ psychological counselling into a problem of solving boundary value problems of fractional differential equations. Studies have shown that using fractional differential equations to analyse the causes of college students’ psychological barriers has an essential role in eliminating college students’ psychological barriers.