The modification of anode material for direct borohydride fuel cell

Abstract

The direct borohydride fuel cell (DBFC) is a promising device that converts chemical energy into electricity by electrochemical reactions. This type of power source is technically more simple than traditional fuel cells, because it does not require any hydrogen container and noble metals. Hydrogen evolution during hydrolysis can be inhibited by modification of anode materials. Extensive studies are focused on various specific electrocatalysts and their impact on oxidation and hydrolysis of borohydride. The aim of the study is to determine the effect of anode material composition using borohydride as a fuel. In order to enhance the utilization of borohydride fuel, AB 5 -type alloy (LaMnNi 3.55 Al 0.30 Mn 0.40 Co 0.75 ) was modified by adding Si or two kinds of carbon materials using the ball milling method. The most proper electrolyte was selected. The physical and electrochemical properties of anode materials were evaluated by scanning electron microscopy (SEM), cyclic voltammetry, chronopotentiometric measurements and electrochemical impedance spectroscopy. Studies showed that graphite was the best additive to anode material due to its density, compact structure and improvement of conductivity.

Control of hydrogen release during borohydride electrooxidation with porous carbon materials

“…9). In our previous studies, 102 we also used MWCNTs as a useful additive to develop the electrochemical properties of anode material. The network formed by MWCNTs created an electron conductive pathway between the hydrogen storage alloy particles.…”