2017
DOI: 10.1515/zkri-2017-2050
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The monoclinic superstructure of the M 2Pt6Al15 series (M=Ca, Sc, Y, La, Lu)

Abstract: The five ternary intermetallic compounds

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Cited by 17 publications
(19 citation statements)
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“…The RE 2 Pt 6 X 15 ( X = Al, Ga) compounds all crystallize as a monoclinic superstructure of the hexagonal RE 0.67 Pt 2 Al 5 (≡ RE 2 Pt 6 Al 15 ) series ( RE = Y, Gd–Tm; P 6 3 / mmc ) described in the literature. Recently, we reported on the crystal structure of Sc 2 Pt 6 Al 15 . The hexagonal subcell is readily found by standard indexing routines, however, additional reflections are evident in the hk 0 planes from the reconstructed diffraction patterns in single crystals obtained using our synthetic conditions.…”
Section: Resultsmentioning
confidence: 92%
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“…The RE 2 Pt 6 X 15 ( X = Al, Ga) compounds all crystallize as a monoclinic superstructure of the hexagonal RE 0.67 Pt 2 Al 5 (≡ RE 2 Pt 6 Al 15 ) series ( RE = Y, Gd–Tm; P 6 3 / mmc ) described in the literature. Recently, we reported on the crystal structure of Sc 2 Pt 6 Al 15 . The hexagonal subcell is readily found by standard indexing routines, however, additional reflections are evident in the hk 0 planes from the reconstructed diffraction patterns in single crystals obtained using our synthetic conditions.…”
Section: Resultsmentioning
confidence: 92%
“…Unit cell parameters a and c and unit cell volume V of the hexagonal subcell of the ( top ) RE 2 Pt 6 Al 15 ( RE = Y, Ce–Nd, Sm, Gd–Lu) and ( bottom ) RE 2 Pt 6 Ga 15 ( RE = Y, La–Nd, Sm, Gd–Lu) series. The lattice parameters of Y 2 Pt 6 Al 15 , La 2 Pt 6 Al 15 and Lu 2 Pt 6 Al 15 as well as Eu 2 Pt 6 Al 15 and Eu 2 Pt 6 Ga 15 are taken from the literature. A comparison with all other reported unit cell parameters is given in Table 1.…”
Section: Resultsmentioning
confidence: 99%
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