For a reduced one-dimensional complete local k-algebra R, Huneke et al. (Res. Math. Sci., 8(4), paper no. 60, 2021) introduced an important invariant, the reduced type. In this article, we study the extremal behavior of reduced type of some special numerical semigroup rings. For a numerical semigroup ring, the behavior of reduced type can be studied by analyzing the set of pseudo-Frobenius elements of the numerical semigroup. We give complete descriptions of pseudo-Frobenius elements of Bresinsky's numerical semigroups and duplication of numerical semigroups. Further, we explore the extremal behavior of reduced type for the associated semigroup rings.