2006
DOI: 10.1021/la0624992
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The Movement of a Water Droplet on a Gradient Surface Prepared by Photodegradation

Abstract: A hydrophobic to hydrophilic gradient surface was prepared using the tuned photodegradation of an alkylsilane self-assembled monolayer (SAM) using irradiation of vacuum ultraviolet light (wavelength=172 nm). The water contact angle on the photodegraded SAM surface was adjusted using the intensity and time photoirradiation parameters. The formation of a gradient was confirmed by fluorescent labeling. The water drop moved from the hydrophobic to hydrophilic surface with a velocity that depended on the gradient. … Show more

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Cited by 158 publications
(113 citation statements)
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References 50 publications
(73 reference statements)
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“…34,35,37 This abrupt increase in wettability, and thus decrease of hydrophobic surface energy, is the result of SAM degradation, under UV-light exposure. 34,35 This shift in water CA measurements between exposed and not exposed SAM can qualitatively explain the transition of LC anchoring from homeotropic to approximately planar.…”
Section: Resultsmentioning
confidence: 99%
“…34,35,37 This abrupt increase in wettability, and thus decrease of hydrophobic surface energy, is the result of SAM degradation, under UV-light exposure. 34,35 This shift in water CA measurements between exposed and not exposed SAM can qualitatively explain the transition of LC anchoring from homeotropic to approximately planar.…”
Section: Resultsmentioning
confidence: 99%
“…Our motivation is to realize a sperm testing device based on the droplet manipulation on a switchable surface. Conventionally, switchable surfaces utilize changes in molecular conformation of a selfassembled monolayer (SAM) under external stimuli [1][2][3][4][5][6][7][8][9][10][11]. However, a fluidic drop usually refuses to move toward more hydrophilic regions on the SAM-based switchable surfaces because the weak chemical gradient cannot overcome the hysteresis of the surface.…”
Section: Introductionmentioning
confidence: 99%
“…In the first case, droplets are formed and manipulated on a surface or interface through the modulation of surface stresses by thermal [26], electrical [27], optical [12], photoresponsive [28] or chemical means [29]. Heat carried by a focused laser beam was also used to move droplets [30] or continuous fluid interfaces [31] on liquid or solid substrates, thus simplifying microfabrication since actuators are not embedded in the substrate anymore.…”
Section: Introductionmentioning
confidence: 99%