The N-methylpyrrolidone–(C1–C10) alkan-1-ols solvent systemsElectronic Supplementary Information (ESI) available: Properties of pure components, densities, viscosities and refractive indices of mixtures NMP(1) + alkan-1-ols(2) at 298.15 K (Tables S1–S4). See http://www.rsc.org/suppdata/cp/b1/b109709c/

Preferential Solvation in Ternary Solutions Containing Methylbenzoate. A Kirkwood−Buff Fluctuation Theory Study

“…Table S2 (Supporting Information) lists density, viscosity, and refractive index measurements for the x hexane/(1 − x ) cyclohexane mixed solvent as a function of composition, along with the derived excess and mixing properties; the properties for the other two binary constituents, x hexane/(1 − x ) MB and x cyclohexane/(1 − x ) MB, were reported elsewhere. , Table S3 lists same properties (Supporting Information) for the x 1 hexane/ x 2 cyclohexane/(1 − x − x 2 ) MB ternary system.…”

“…Accurate data pairs of three macroscopic properties are needed for a proper evaluation of KBIs: isothermal compressibility, activity coefficient, and partial molar volume. Evaluation of partial molar volumes for binary and ternary solvents can be properly achieved by application of the intercept method to excess molar volumes. , On the other hand, the contribution of isothermal compressibility of the ternary mixture to KBIs was negligible in this work (ideal behavior), so the values for this property were deduced from those of pure components available in the literature . Evaluation of activity coefficients, normally from data of vapor−liquid equilibria, is costly and time-consuming.…”

“… a Parameters for hexane + MB are taken from ref , and those for cyclohexane + MB are taken from ref . …”

“…These solvents are widely used in polymer science and syntheses operations; however, the scarce literature existing makes convenient a systematic research on their properties . Density, dynamic viscosity, and refractive index data of the methylbenzoate/cyclohexane/ n -hexane ternary solvent and its constituent n -hexane/cyclohexane, n -hexane/methylbenzoate, and cyclohexane/methylbenzoate binary components are reported over the full composition range. , From these measurements, the excess and mixing properties were evaluated and interpreted on the basis of interactions and geometry factors. The volumetric properties of the binary systems were correlated using the cubic equations of state by Soave (SRK) and Peng−Robinson (PR) combined with two simple mixing rules.…”

PVTx Measurements of the N-Methylpyrrolidone/Methanol Mixed Solvent: Cubic and SAFT EOS Analyses

“…Over the past years our group has conducted a systematic study on the thermophysical properties of NMP-containing mixtures, both at atmospheric − and high pressures. To properly analyze the selectivity and capability of NMP, the research performed on the PVT behavior of the NMP/water binary mixture 19 is extended in this work to the NMP/methanol mixed solvent over the full composition range, between 278.15 and 358.15 K and pressures up to 60 MPa.…”