A high-power laser system is employed to drive the fusion ignition to realize sustainable supply of green energy according to the inertial confinement fusion theory, in which frequency-converting crystals are sealed in the terminal vacuum chamber and utilized to turn the incident laser (1053 nm) to the desired one (351 nm). However, the reflected 351 nm laser from the pellet hohlraum that goes back through the frequency-converting crystal is found to be harmful for the upstream elements that are located before the terminal chamber. In this study, a specialized coating system for the frequency-converting crystals was designed and fabricated to both ensure high output power for the fusion and reduce the reflected 351 nm laser energy by absorption. Furthermore, the structural, mechanical, and laser-damage resistant properties of this coating were investigated as well.