2009
DOI: 10.1107/s0108270109015054
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The neutral cluster amminehexa-μ2-chlorido-μ4-oxido-tris(1,4,6-triazabicyclo[3.3.0]oct-4-ene)tetracopper(II)

Abstract: The title compound, [Cu(4)Cl(6)O(C(5)H(9)N(3))(3)(NH(3))], is a neutral conformationally chiral cluster which crystallizes under the conditions described in this paper as a racemic conglomerate. It contains four Cu(II) atoms in a tetrahedral coordination with a central O atom lying on a crystallographic threefold axis. Six chloride anions bridge the four Cu(II) atoms. Three Cu(II) atoms are bound by an N atom of a monodentate 1,4,6-triazabicyclo[3.3.0]oct-4-ene (Htbo) ligand and the remaining Cu(II) atom is bo… Show more

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Cited by 5 publications
(1 citation statement)
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“…The tetranuclear copper motif, L 4 Cu 4 Cl 6 O, where L is a nitrogen-containing Lewis base ligand, is common. For instance, several structures have been reported in which L contains either an imidazole or substituted imidazole moiety (Clegg et al, 1988;Norman et al, 1989Erdonmez et al, 1990Atria et al, 1999;Corté s et al, 2006;Chiarella et al, 2009Chiarella et al, , 2010She et al, 2010) or a benzimidazole moiety (Tosik et al, 1991Zhang et al, 2003Jian et al, 2004;Li et al, 2011).…”
Section: Database Surveymentioning
confidence: 99%
“…The tetranuclear copper motif, L 4 Cu 4 Cl 6 O, where L is a nitrogen-containing Lewis base ligand, is common. For instance, several structures have been reported in which L contains either an imidazole or substituted imidazole moiety (Clegg et al, 1988;Norman et al, 1989Erdonmez et al, 1990Atria et al, 1999;Corté s et al, 2006;Chiarella et al, 2009Chiarella et al, , 2010She et al, 2010) or a benzimidazole moiety (Tosik et al, 1991Zhang et al, 2003Jian et al, 2004;Li et al, 2011).…”
Section: Database Surveymentioning
confidence: 99%