2005
DOI: 10.1016/j.jpowsour.2004.11.050
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The Ni3Sn4 intermetallic as a novel electrode in lithium cells

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Cited by 85 publications
(51 citation statements)
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“…As seen in the figure, the reduction peak in the potential at 0.2 V is assumed to be due to the electrochemical reaction of Sn component in the Co y Sn alloy involving the formation of the Li x Sn alloy and the separation of Co according to Eq. (1) [13,14]. In contrast, the oxidation peaks corresponding to the reduction peak at 0.20 V were observed at 0.50 and 0.70 V. These peaks may be due to a dealloying reaction from Li x Sn to form Li and Sn according to Eq.…”
Section: Resultsmentioning
confidence: 98%
“…As seen in the figure, the reduction peak in the potential at 0.2 V is assumed to be due to the electrochemical reaction of Sn component in the Co y Sn alloy involving the formation of the Li x Sn alloy and the separation of Co according to Eq. (1) [13,14]. In contrast, the oxidation peaks corresponding to the reduction peak at 0.20 V were observed at 0.50 and 0.70 V. These peaks may be due to a dealloying reaction from Li x Sn to form Li and Sn according to Eq.…”
Section: Resultsmentioning
confidence: 98%
“…For such stoichiometry the relative equilibrium binary phase diagram foresees the existence of the monoclinic Ni 3 Sn 4 structure (JCPDS 4-851) from 273 K up to 1070 K [6]. The XRD patterns sequence, reported in Fig.…”
Section: Resultsmentioning
confidence: 94%
“…We initially focused our attention on the NiSn system, and in particular on the Ni 44 Sn 56 atomic % composition, selected in light of its good electrochemical performance [6,20]. For such stoichiometry the relative equilibrium binary phase diagram foresees the existence of the monoclinic Ni 3 Sn 4 structure (JCPDS 4-851) from 273 K up to 1070 K [6].…”
Section: Resultsmentioning
confidence: 99%
“…Sn Ni alloy can be prepared by di erent technique such as electrodeposition [5], sintering [6], ball milling [7]. In comparison, the electrodeposition presents signi cant advantages, particular * corresponding author; e-mail: mehmetu@sakarya.edu.tr for the preparation materials of Li-ion battery.…”
Section: Introductionmentioning
confidence: 99%