Density and viscosity
measurements are performed for ethanol, water,
hexamethyldisiloxane (MM), octamethyltrisiloxane (MDM), decamethyltetrasiloxane
(MD2M), and their mixtures (ethanol/water, MM/MDM, MM/MD2M, MDM/MD2M) at 100 kPa at different temperatures
(293–423 K) and mixture compositions. To measure the density
and viscosity, an IMETER measuring system with a combined dynamic
and static force measurement method, a density meter with an oscillating
U-tube measuring method, and a rheometer with a double-gap measuring
system were used. The experimentally determined data for the pure
substances show a very good agreement with literature data. However,
there is a strong deviation of the mixture viscosity between max 7%
for MM/MDM and 31% for MM/MD2M compared to Refprop v.10.0.
In order to enable an improvement in the calculation of the density
and viscosity for the mixtures, specific parameters for the Jouyban–Acree
model are developed for all mixtures and thereby, a better description
of the density and viscosity for the mixtures could be achieved.