The nitration of 1-methyl-2,4,5-triiodoimidazole and its oxidation by-product under nitration conditions

Lian, Peng; Chen, Lizhen; Chen, Jun; Wang, Jingqi; Wang, Jianlong; Chen, Jian

doi:10.1080/07370652.2020.1827313

Cited by 8 publications

(1 citation statement)

References 39 publications

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“…Many of the aforementioned single-block iodinated BEMs, named as "first generation ADWs" suffer from a structural constraint about how to realize an optimal trade-off between iodine and energy-carrier bonds [74]. This amounts to saying that, owing to a limited number of bonding sites in a single-block structure, the higher the number of -I bonds, the fewer are the sites available for energy-carrier groups, such as, for example, -NO 2 .…”

Section: Iodinated Moleculesmentioning

confidence: 99%

Organic and Inorganic Biocidal Energetic Materials for Agent Defeat Weapons: An Overview and Research Perspectives

et al. 2023

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A critical survey concerning biocidal energetics is proposed according to a classification depending on their chemical structure. The need of optimizing the performances of such compounds is an important target for the inertization of biological weapons, requiring a synergy between the thermal effects of combustion/detonation with the biocidal effects of reaction products released into the environment. The main physicochemical aspects related to the synthesis technique, the thermodynamic variables and the antimicrobial activity have been discussed and compared. In particular, different kinds of biocides have been taken into account, with particular attention to the role of iodine as one of the most promising and eco-friendly chemical species to this purpose, in line with the paradigms of environmental protection and the rational utilization of chemicals. Furthermore, the protocols adopted to assess the effectiveness of biocidal agents have been thoroughly examined according to the recent studies proposed by some of the most reputable research groups in the field. Finally, some insights for future investigations are proposed.

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Section: Iodinated Moleculesmentioning

confidence: 99%

Organic and Inorganic Biocidal Energetic Materials for Agent Defeat Weapons: An Overview and Research Perspectives

et al. 2023

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Imidazole‐Based Energetic Materials: A Promising Family of N‐Heterocyclic Framework

Xie

Pei

Cai

et al. 2022

Chemistry An Asian Journal

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Imidazole represents a fascinating class of explosophoric units with exciting structures and unique properties. As compared to other nitrogen-rich heterocycles, imidazole demonstrates great potential applications due to economic effectiveness and superior energetic performances. The field of traditional chemistry has been extensively explored for imidazole, and thus established bond-building methods and functionalization strategies promote further development as high-energy density materials (HEDMs). This review addresses the development of energetic imidazole compounds in the past decade, summarizes their physiochemical properties, and is divided into three parts (explosives, propellants, and energetic biocides) according to application requirements. Various synthetic strategies for these energetic molecules are highlighted, including the construction of heterocyclic frameworks and following functionalization. The selected and discussed reactions illustrate the versatility of imidazole in energetic applications as building blocks for the future design of new HEDMs.

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Facile synthesis of three kinds triazole salts of 2,4,5-trinitroimidazole and their thermal decomposition properties

Lian

Chen

Huang³

et al. 2021

Journal of Energetic Materials

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The nitration of 1-methyl-2,4,5-triiodoimidazole and its oxidation by-product under nitration conditions

Cited by 8 publications

References 39 publications

Organic and Inorganic Biocidal Energetic Materials for Agent Defeat Weapons: An Overview and Research Perspectives

Organic and Inorganic Biocidal Energetic Materials for Agent Defeat Weapons: An Overview and Research Perspectives

Imidazole‐Based Energetic Materials: A Promising Family of N‐Heterocyclic Framework

Facile synthesis of three kinds triazole salts of 2,4,5-trinitroimidazole and their thermal decomposition properties

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