In this paper we consider the Klebanov-Tseytlin background and its non-Abelian T-dual geometry along a suitably chosen SU(2) subgroup of isometries. We analyse the Penrose limits along various null geodesics of both the geometries. We observe that, the Klebanov-Tseytlin geometry does not admit any pp-wave solutions. However, the T-dual background gives rise to pp-wave solution upon taking the Penrose limit along some appropriate null geodesic. We comment on the possible gauge theory dual for our pp-wave background.