Generally, optical diffraction is only weakly dependent on the refractive index of a medium in which light propagates. In this paper, diffraction in a nearly isotropic Kerr photonic crystal (PhC) made of silicon pillars embedded in nonlinear carbon disulfide ambient was reversed and enhanced by its linear refractive index, which is negative and much less than unity. The effective nonlinear refractive index coefficient n 2 of the PhC was found by fitting spectral broadening induced by self-phase modulation. The enhanced inverse diffraction, attributed to positive n 2 , allows self-defocusing in one single PhC. More interestingly, the same PhC can selectively exhibit dual functionalities, i.e., self-defocusing and self-focusing, based on the wavefront property of a given input beam. Our results may pave the way for protecting nanostructured photonic devices from laser damage and provide a method for controlling wavefronts.