The optical properties and photocatalytic activity of CdS-ZnS-TiO2/Graphite for isopropanol degradation under visible light irradiation

Rahmawati, Fitria; Wulandari, Rini; Murni, Irvinna Mutiara; Mudjijono,

doi:10.1063/1.4941466

Cited by 1 publication

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“…Photocatalysis is a potential method to overcome many problems in chemical pollution such as organic waste degradation and dye molecules degradation. TiO 2 is a well-known photocatalyst used either as a single photocatalyst powder, or in a composite form such as TiO 2 /carbon [1], ZnS-CdS/TiO 2 [2], and nano-CdS/TiO 2 [3]. Titanium dioxide (TiO 2 ) or titania is a very well-known and well-researched material due to the stability of its chemical structure, biocompatibility, physical, optical and electrical properties [4].…”

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confidence: 99%

The Photocatalytic Activity of Zns-TiO2 on a Carbon Fiber Prepared by Chemical Bath Deposition

2019

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This research prepared a TiO2, ZnS, and ZnS-TiO2 film on a carbon fiber, to produce TiO2/C-fiber, ZnS-C-fiber, and ZnS-TiO2/C-fiber by Chemical Bath Deposition (CBD). Results show that TiO2/C-fiber consist of anatase at 2θ 25.3 o and 54.6 o, rutile at 2θ 43.5 o and a carbon characteristic peak at 2θ of 24.5 o. Meanwhile, the characteristic peaks of ZnS on ZnS-TiO2/C-fiber present at 2θ of 27.91 o and 54.58 o. TiO2/C-fiber has a band gap energy of 3.60 eV, the ZnS/C-fiber of 3.73 eV; when those two catalyst combine, the gap energy is 3.15 eV indicating the interface charge transfer between ZnS-TiO2. Photocatalytic treatment of an isopropanol solution with TiO2/C-fiber as a catalyst and under UV light radiation present results peaks at 222- 224 nm and 265 nm, indicating the electronic transition of acetone. Meanwhile, the isopropanol degradation with ZnS-TiO2/C-fiber produced a new peak at 234-237 nm. The Quantum Yield, QY, of ZnS-TiO2/C-fiber is 6.96 x 10-4, higher than TiO2/C-fiber, i.e., 0.42 x 10-4. It indicates that ZnS provides a significant role in the photocatalytic activity through a red shift of light response and decreasing electron-hole recombination.

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