<span lang="EN-GB">Using a high temperature solid-state technique, various phosphors Sr<sub>4</sub>La(PO<sub>4</sub>)<sub>3</sub>O:Ce<sup>3+</sup>, Tb<sup>3+</sup>,Mn<sup>2+</sup> (SLPO:Ce,Tb,Mn) were produced. In Sr<sub>4</sub>La(PO<sub>4</sub>)<sub>3</sub>O, the luminescence characteristics, thermal stability, and energy conversion between Ce<sup>3+ </sup>and Tb<sup>3+</sup>-Mn<sup>2+ </sup>have been thoroughly studied. The sensitizer Ce<sup>3+</sup> particles inclusion could considerably improve the feeble Tb<sup>3+</sup> green radiation and Mn<sup>2+</sup> red radiation via energy transfer. By adjusting the scale of Ce<sup>3+</sup>/Tb<sup>3+</sup> over Ce<sup>3+</sup>/Mn<sup>2+</sup> atoms, the color of the emission may be changed. White light was produced in the Sr<sub>4</sub>La(PO<sub>4</sub>)<sub>3</sub>O:0.12Ce<sup>3+</sup>,0.3Mn<sup>2+</sup> specimen with chromatism coordinates of (0.3326, 0.3298), showing that the phosphors SLPO:Ce,Tb,Mn possess promising application on WLEDs. The conclusion is supported by Mie-scattering theory and Lambert-Beer's law.</span>