The Origin of Amphipathic Nature of Short and Thin Pristine Carbon Nanotubes—Fully Recyclable 1D Water‐in‐Oil Emulsion Stabilizers

Abstract

Short and thin pristine carbon nanotubes (CNTs) emerge as 1D emulsion stabilizers capable of replacing aquatoxic low‐molecular surfactants. However, inconsistencies in understanding of water–solid interfaces for realistic CNTs hamper their individualization‐driven functionalities, processability in benign media, and compatibility with a broad‐scale of matrices. Pristine CNT processing based on water and inexpensive n‐alkanes within a low energy regime would constitute an important step toward greener technologies. Therefore, structural CNT components are quantitatively assessed, placing various CNTs on the scale from hydrophobicity to hydrophilicity. This structural interweave can lead to amphipathicity enabling the formation of water‐in‐oil emulsions. Combining experiments with theoretical studies, CNTs and CNT emulsions are comprehensively characterized establishing descriptors of the emulsifying behavior of pristine and purified CNTs. They emerge as having hydrophilic open‐ends, small number of oxygen–functionalized/vacancy surface areas, and hydrophobic sidewalls and full caps. The interplay of these regions allows short and thin CNTs to be utilized as fully recyclable 1D surfactants stabilizing water/oil emulsions which, as demonstrated, can be applied as paints for flexible conductive coatings. It is also shown how the amphipathic strength depends on CNT size, the pristine‐to‐oxidized/vacancy domains and the oil‐to‐water ratios.

Towards the superlubricity of polymer–steel interfaces with ionic liquids and carbon nanotubes

“…Unfortunately, Al2O3 is characterised by high hardness, and its presence, even on the nanoscale, may have a very negative impact on wear mechanisms in the contact zone [34]. Therefore, before the process of combining with the liquid phase, the MWCNTs were purified to remove Al2O3 [45]. SEM images of MWCNTs before and after purification are shown in Figure 1.…”

Recyclable Fe3O4 Nanoparticles Responsive to Temperature for Heavy Oil Viscosity Reduction: Synthesis, Characterization, and Performance

“…They are more cost-effective than surfactants as emulsifiers to reduce environmental impacts. In addition, due to their small size, nanoparticles can pass through smaller pores and narrow throats that cannot be reached by large-sized materials, such as SiO 2, , Fe 3 O 4, , TiO 2, Al 2 O 3, − GO, , cellulose, , lignin, carbon nanotubes, etc. Jia et al successfully synthesized amphiphilic Janus-SiO 2 nanoparticles to obtain stable O/W/O Pickering emulsions, which showed excellent enhanced oil recovery of 27.2% in the core flooding test.…”