2021
DOI: 10.1002/ange.202102313
|View full text |Cite
|
Sign up to set email alerts
|

The Origin of Catalytic Benzylic C−H Oxidation over a Redox‐Active Metal–Organic Framework

Abstract: Selective oxidation of benzylic CÀH compounds to ketones is important for the production of a wide range of fine chemicals, and is often achieved using toxic or precious metal catalysts. Herein, we report the efficient oxidation of benzylic C À H groups in a broad range of substrates under mild conditions over a robust metal-organic framework material, MFM-170, incorporating redox-active [Cu 2 II (O 2 CR) 4 ] paddlewheel nodes. A comprehensive investigation employing electron paramagnetic resonance (EPR) spect… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Publication Types

Select...

Relationship

0
0

Authors

Journals

citations
Cited by 0 publications
references
References 37 publications
0
0
0
Order By: Relevance

No citations

Set email alert for when this publication receives citations?