INTRODUCTIONVolatile components enter the atmosphere, oceans, and other surface waters through pre-, syn-, and post-eruptive volcanic processes that involve a variety of fl uids. Aluminosilicate-poor fl uids include aqueous or carbonic to sulfi de-, sulfate-, chloride-, fl uoride-, carbonate-, and phosphate-rich compositions in volcanic environments, but other more complex combinations of these constituents may be involved (Giggenbach 1977;Roedder 1984 Roedder , 1992Lowenstern 1995). Other, rare gases and dissolved constituents (e.g., H 2 , N 2 , He, Ar, H 3 BO 3 , Hg, CH 4 and other hydrocarbon compounds, metals, and metalloids) are also present, but in general they are not suffi ciently concentrated to form their own phases or control bulk-fl uid composition and volcanic processes. As a result of their diverse compositions, volcanic fl uids ranging from vapor to liquid exhibit widely different densities and show strong distinctions in heat capacity, dielectric behavior, viscosity, and other chemical and physical characteristics (Geiger et al. 2006a). The density of a saline liquid in the system NaCl-H 2 O at 50 MPa and 800 °C, for example, is more than 7 times that of the coexisting aqueous vapor (e.g., 0.2 gm/cm 3 ) (Henley and McNabb 1978).Multiple fl uids move, mix, and/or unmix in magma chambers and volcanic conduits, in the root zone of fumaroles, and in the convective hydrothermal systems that are ubiquitous to volcanic environments. Hydrothermal systems are typically centered on magmatic intrusions and may include crater lakes at the top of eruptive conduits. Hydrothermal processes involving two or more fl uid phases operate through a variety of geologically relevant, shallowcrustal pressure-temperature-composition conditions. Volcanic fl uids occur at supersolidus to subsolidus conditions, meaning that the dense aluminosilicate melt that is common to volcanism may or may not be present. This chapter addresses the evidence for and occurrence of two or more low-density, aluminosilicate-poor fl uids in volcanic and related environments. It also describes the role of multiple fl uids in the chemical and physical processes that occur in these environments-even though many aspects of volcanic processes are still poorly understood.
BACKGROUND