2006
DOI: 10.1021/cm061032+
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The Origin of the High Conductivity of Poly(3,4-ethylenedioxythiophene)−Poly(styrenesulfonate) (PEDOT−PSS) Plastic Electrodes

Abstract: The development of printed and flexible (opto)electronics requires specific materials for the device's electrodes. Those materials must satisfy a combination of properties. They must be electrically conducting, transparent, printable, and flexible. The conducting polymer poly(3,4-ethylenedioxythiophene)− poly(styrenesulfonate) (PEDOT−PSS) is known as a promising candidate. Its conductivity can be increased by 3 orders of magnitude by the secondary dopant diethylene glycol (DEG). This “secondary doping” phenome… Show more

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Cited by 865 publications
(728 citation statements)
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“…[4,[22][23][24][25] Conductive polymers such as poly (3,4-ethylenedioxythiophene) doped with polystyrene sulfonic acid (PEDOT:PSS) also partially offer both intrinsic properties. [26][27][28] A second strategy consists of dimensional engineering using conductive, but not necessarily transparent materials (e.g., metals or carbon-based materials [29] ) and their arrangement in such a way that the system conducts in one direction and is transparent in the other. This is achieved by arranging the conductive material in either a very thin layer or a mesh of (nano-)wires.…”
Section: Materials Systems For Transparent Electrodesmentioning
confidence: 99%
“…[4,[22][23][24][25] Conductive polymers such as poly (3,4-ethylenedioxythiophene) doped with polystyrene sulfonic acid (PEDOT:PSS) also partially offer both intrinsic properties. [26][27][28] A second strategy consists of dimensional engineering using conductive, but not necessarily transparent materials (e.g., metals or carbon-based materials [29] ) and their arrangement in such a way that the system conducts in one direction and is transparent in the other. This is achieved by arranging the conductive material in either a very thin layer or a mesh of (nano-)wires.…”
Section: Materials Systems For Transparent Electrodesmentioning
confidence: 99%
“…We obtained a mean value of 92 m for the PEDOT:PSS and 0.60 m for the nanoparticle silver. The lower resistivity of the PEDOT:PSS with respect to the pristine PEDOT:PSS is justified by the presence of the diethylene glycol (DEG) in the liquid ink [27,28]. Indeed, DEG induces to create a highly conducting PEDOT:PSS network.…”
Section: Preparation Of Sensing Filmsmentioning
confidence: 99%
“…1.3 wt.-% PEDOT:PSS coating dispersion (Baytron P HC), diethyleneglycol (DEG) [26] and fluorosurfactant (Zonyl FS-300) were purchased from H.C. Starck, Sigma-Aldrich and DuPont, respectively, and were used as received without further purification. The three material components were mixed according to a weight ratio of PEDOT:PSS/DEG/FS-300 = 95/5/0.1 wt.-% and then extensively stirred (hereinafter called coating dispersion).…”
Section: Preparation Of Ec Display Devicesmentioning
confidence: 99%