1988
DOI: 10.1016/s0040-4039(00)80531-6
|View full text |Cite
|
Sign up to set email alerts
|

The oxidation of aromatic amines in the presence of “electron-rich” aromatic systems

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1

Citation Types

0
22
0

Year Published

1992
1992
2020
2020

Publication Types

Select...
5
5

Relationship

0
10

Authors

Journals

citations
Cited by 58 publications
(22 citation statements)
references
References 8 publications
0
22
0
Order By: Relevance
“…Firstly we focused our attention on Oxone® that recently has showed great efficiency to promote oxidative fissions of aromatic rings . Umbelliferone ( 1b ) was treated with this peroxyacid and acetone in basic medium because these conditions are well‐known as generator system of dimethyldioxirane in situ, another effective oxidant to carry out the cleavage of benzene rings,[12c] and therefore, to take advantage of the oxidizing capacity of two different reagents. Both stoichiometry of Oxone® (5–10 equiv.)…”
Section: Resultsmentioning
confidence: 99%
“…Firstly we focused our attention on Oxone® that recently has showed great efficiency to promote oxidative fissions of aromatic rings . Umbelliferone ( 1b ) was treated with this peroxyacid and acetone in basic medium because these conditions are well‐known as generator system of dimethyldioxirane in situ, another effective oxidant to carry out the cleavage of benzene rings,[12c] and therefore, to take advantage of the oxidizing capacity of two different reagents. Both stoichiometry of Oxone® (5–10 equiv.)…”
Section: Resultsmentioning
confidence: 99%
“…For example, when such amines are oxidized, one would obtain a variety of higher oxygenated products such as hydroxylamine, nitroso compound, or oxime. Although there are many reports of such oxidations available in the literature, [30][31][32][33][34][35][36][37][38][39] the existing methods suffer from low yields of oximes.…”
Section: Oxidation Of N-h Bonds Of Organic Aminesmentioning
confidence: 99%
“…It is commonly used as Oxone (2KHSO 5 -KHSO 4 -K 2 SO 4 ) and is a versatile oxidant for the transformation of a wide range of functional groups [29]. Recent reports have dealt with the use of a triple salt of potassium peroxomonosulfate, which can be used for the oxidation of alkenes [30], arenas [31], amines [32], imine [33], sulfides [34], selenides [35], -amino acids [36], and acetals [37]. Oxone is a relatively stable peroxygen, and loses less than 1% of its activity per month when stored under appropriate conditions.…”
Section: Introductionmentioning
confidence: 99%