The oxidation of propene over bismuth oxide, molybdenum oxide, and bismuth molybdate catalysts

Peacock, J. M.; Parker, A. J.; Ashmore, P. G.; Hockey, J. A.

doi:10.1016/0021-9517(69)90306-6

Cited by 26 publications

(2 citation statements)

References 12 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Later, they were found to be capable of catalyzing the ammoxidation of propylene to acrylonitrile and the oxidation of propylene to acrolein . Their potential for further catalytic processes was extensively studied thereafter . Nowadays, they have became popular catalysts for the oxidation of light hydrocarbons .…”

Section: Introductionmentioning

confidence: 98%

Sol–Gel Synthesis of Bismuth Molybdate Catalysts for the Selective Oxidation of Propylene to Acrolein: Influence of pH Value and Theoretical Molar Atomic Ratio

Hung

Truong

et al. 2017

J Chinese Chemical Soc

View full text Add to dashboard Cite

Different bismuth molybdate catalysts for the selective oxidation of propylene to acrolein were prepared by the sol–gel method, starting from bismuth nitrate, ammonium molybdate, and citric acid. The influence of pH value and theoretical molar Bi/Mo atomic ratio on the complexation and gelation is surveyed using IR spectroscopy, X‐ray diffraction, and BET. Their catalytic activities for the conversion propylene to acrolein are examined.

show abstract

Section: Introductionmentioning

confidence: 98%

Sol–Gel Synthesis of Bismuth Molybdate Catalysts for the Selective Oxidation of Propylene to Acrolein: Influence of pH Value and Theoretical Molar Atomic Ratio

Hung

Truong

et al. 2017

J Chinese Chemical Soc

View full text Add to dashboard Cite

show abstract

“…Isotope labeling studies using 18 O have been performed since 1970s on silicasupported bismuth molybdate catalysts. Different phases of bismuth molybdate (gamma, alpha, and their mixtures) with various loadings up to 50% wt have been investigated for the oxidation of propylene [10,[13][14][15]. However, no consensus has been obtained about which loadings resulted in the most effective catalysts.…”

Section: Introductionmentioning

confidence: 99%

Selective oxidation of propylene to acrolein by silica-supported bismuth molybdate catalysts

Duc

Fehrmann

et al. 2011

Res Chem Intermed

View full text Add to dashboard Cite

Silica-supported bismuth molybdate catalysts have been prepared by impregnation, structurally characterized and examined as improved catalysts for the selective oxidation of propylene to acrolein. Catalysts with a wide range of loadings (from 10 to 90 wt%) of beta bismuth molybdate (b-Bi 2 Mo 2 O 9 ) were studied to provide a better understanding about the distribution of active sites, and to elucidate the role of lattice oxygen in the reaction. The catalyst containing 50 wt% of beta bismuth molybdate on SiO 2 was found to possess good distribution of active sites and sufficiently high lattice oxygen, which resulted in an extraordinary increase of the catalytic activity.

show abstract

Surface Sites in Heterogeneous Catalysis

Morrison

1977

The Chemical Physics of Surfaces

View full text Add to dashboard Cite

The oxidation of propene over bismuth oxide, molybdenum oxide, and bismuth molybdate catalysts

Cited by 26 publications

References 12 publications

Sol–Gel Synthesis of Bismuth Molybdate Catalysts for the Selective Oxidation of Propylene to Acrolein: Influence of pH Value and Theoretical Molar Atomic Ratio

Sol–Gel Synthesis of Bismuth Molybdate Catalysts for the Selective Oxidation of Propylene to Acrolein: Influence of pH Value and Theoretical Molar Atomic Ratio

Selective oxidation of propylene to acrolein by silica-supported bismuth molybdate catalysts

Surface Sites in Heterogeneous Catalysis

Contact Info

Product

Resources

About