“…The 12 elements and compounds selected for statistical analysis (Al 2 O 3 , SiO 2 , K2O, CaO, Ti, Fe, Mn, Cu, Zn, Rb, Zr, Sr) have good reliability in pXRF analysis and show low error margins (Al 2 O 3 , Sr ≤ 5%; SiO 2 , CaO, Fe < 1%; K 2 O, Ti, Zr ≤ 2%; Mn, Sr ≤ 10%; Cu, Zn and Rb ≤ 20%) (Supporting Information: Table S1). In this assessment, the limitations of the pXRF were carefully considered and included in the consideration of the results (Hunt & Speakman, 2015;Lorenzon & Iacovou, 2019;Shackley, 2011). The pXRF accuracy was further increased by analyzing a control sample.…”