2004
DOI: 10.1039/b313215c
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The paste hydration of brownmillerite with and without gypsum: a time resolved synchrotron diffraction study at 30, 70, 100 and 150 °C

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Cited by 97 publications
(39 citation statements)
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“…The ferrite phase resembles an impure form of the mineral brownmillerite, often considered to be its mineral equivalent. This phase can contain up to 10% impurities and has a significantly variable Al/Fe ratio (Meller et al, 2004). The ferrite tends to be more enriched in ferric-iron in oil well cements than in typical construction cements, and the tricalcium aluminate (cement chemistry notation: C 3 A) is absent or present only in trace amounts (Meller et al, 2004).…”
Section: Wellbore Cement Chemistrymentioning
confidence: 99%
“…The ferrite phase resembles an impure form of the mineral brownmillerite, often considered to be its mineral equivalent. This phase can contain up to 10% impurities and has a significantly variable Al/Fe ratio (Meller et al, 2004). The ferrite tends to be more enriched in ferric-iron in oil well cements than in typical construction cements, and the tricalcium aluminate (cement chemistry notation: C 3 A) is absent or present only in trace amounts (Meller et al, 2004).…”
Section: Wellbore Cement Chemistrymentioning
confidence: 99%
“…, [ 42 ] the hole mobility µ h values of 1.95 × 10 −4 , 2.75 × 10 −4 , and 2.03 × 10 −4 cm 2 V −1 s −1 respectively for the active layers processed with DIO, SH-na, and that without additive but with the dipping treatment. These values are increasingly better than 9.12 × 10 −5 cm 2 V −1 s −1 obtained for the active layer processed without any additive nor the dipping treatment.…”
Section: Correlations Of Hole and Electron Mobility To Morphologymentioning
confidence: 99%
“…Iron is a ubiquitous element in natural environments, and Portland cement clinker contains $5% to 15% ferrite (idealised Ca 2 (Al x Fe 1Àx ) 2 O 5 ). It has been observed in Portland cement systems that Fe(III) partly exchanges for Al(III) in the lattice of ettringite and AFm-phases (Fukuhara et al, 1981;Emanuelson and Hansen, 1997;Csizmadia et al, 2001;Meller et al, 2004). AFm is the cement short hand notation for Ca 4 (Al,Fe) 2 (OH) 12 AE (X)yH 2 O where X denotes two formula units of a singly charged anion or one formula unit of a doubly charged anion.…”
Section: Introductionmentioning
confidence: 99%