The phase transitions near the melting point of sbCL3

Brown, R. J. C.; Gillies, G. C.; Halliwell, R. E.; Segel, S. L.

doi:10.1016/0022-2364(75)90251-6

Cited by 3 publications

(8 citation statements)

References 4 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The corresponding 37C1 NQR lines were also ob served. The frequencies vQ agree with those reported in [6][7][8][9][10][11][12][13][14]. While the vQ of the high frequency line exhibits the usual negative temperature dependence, that of the low frequency line exhibits a much smaller dependence and below 45 K even a slightly positive dependence [10].…”

Section: Resultssupporting

confidence: 88%

“…A phase transition was reported for SbCl3 [23]. Brown et al observed an increase of the line width above room temperature, followed by a sudden drop at 342 K [12]. However the transition point Tx is only a few degrees below Tm and the signal became too week for an exact determination of vQ and Tx there.…”

Section: Resultsmentioning

confidence: 90%

“…X is defined as the amount of p electron which is transferred from the halogen ion to the metal ion in forming covalent bonding and is supposed to produce the EFG with the largest component along the bond [2]. It just corresponds [31] to the number of unbal anced p electrons, / , defined as f = (11) where e2 Q qm ol is the coupling constant for the mole cule and related with the resonance frequency vQ by 2 h 1 + 2 \ 1/2 (12) xocexp( -r/o) (10) Thus, we can compare X determined from Tt with / determined independently from vQ. Values of 0 ~ 0.06 are reported for r] (Cl,) and 0.14 ~ 0.16 for rj (Cl") [9,11,14,25].…”

Section: Estimation Of Covalencymentioning

confidence: 99%

“…3s.37c i NQR of SbCl3 has been reported by many Reprint request to Dr. N. Okubo, Institute of Physics, Uni versity of Tsukuba, Tsukuba, 305 Japan. authors [6][7][8][9][10][11][12][13][14][15]. However, these studies are limited to temperatures below 180 K or above room tempera ture, and do not deal with Tx.…”

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

³⁵Cl Nuclear Quadrupole Relaxation in Antimony Trichloride

Okubo

Abe

1994

Zeitschrift Für Naturforschung A

View full text Add to dashboard Cite

The 35C1 NQR frequency and spin-lattice relaxation time in SbCl3 have been measured between 10 K and the melting point. The relaxation at low temperatures is attributed to the Raman process. A Debye temperature of 141 K and covalencies 0.390 and 0.356 are obtained. The latter values correspond well to those obtained from the NQR frequencies. For the relaxation above 200 K two more mechanisms are considered.

show abstract

Section: Resultssupporting

confidence: 88%

Section: Resultsmentioning

confidence: 90%

Section: Estimation Of Covalencymentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

³⁵Cl Nuclear Quadrupole Relaxation in Antimony Trichloride

Okubo

Abe

1994

Zeitschrift Für Naturforschung A

View full text Add to dashboard Cite

show abstract

“…Several phase transitions have been reported in SbC13, one at a pressure of 350 MPa (121, and others near the melting point at atmospheric pressure (13). No evidence of any of these transitions was found in these measurements; other investigations of the high temperature phase transitions have been reported elsewhere (14).…”

mentioning

confidence: 60%

Nuclear quadrupole resonance and intermolecular interactions: temperature and pressure effects in Group V trichlorides

Gillies¹,

Brown²

1976

Can. J. Chem.

View full text Add to dashboard Cite

GRANT CALLUM GILLIES and RICHARD YULIAN CHALLIS BROWN. Can. J. Chem. 54,2266Chem. 54, (1976.Nuclear quadrupole resonance frequencies for the metal and chlorine atoms in AsC13 and SbCI; have been measured as functions of temperature and pressure. These data are analysed to obtain the isothermal volume dependences and the isochoric temperature dependences of the field gradient parameters. Existing Icnowledge of the Group V trichlorides shows that the strength of intermolecular bonding increases in the order AsC1, < SbCl; < BiC13, and this trend is reflected in the relative importance of volume effects in determining the nqr freq~lencies in these solids. A simple theory of the pressure dependences of nqr frequencies in molecular crystals is proposed, which accounts for all data presentiy available. The pressure coefficient contains static and dynamic contributions which are of opposite signs; the static contributioil is negative and becomes nulnerically larger as the strength of intermolecular bonding increases.GRANT C A L L U~~ GILL~LS et RICHARD JULIAN CHALLIS BROWN. Can. J. Chem. 518, 2266Chem. 518, (1976. On a mesure les frequences de resonance iluclCaire quadrupolaire des atomes mCtalliques et des chlores dans le AsC1; et le SbC13 en fonction de la temperature et de la pression. On a analysC ces donnCes pour obtenir des dCpendances volumiques isothermes et les dipendances isochore de tempkrature pour les paramiitres de gradient de champ. I e s connaissances existantes des trichlorures du groupe V montrent que la force des liaisons intermolCculaires augmente dans l'ordre AsCi, < SbC13 < BiC13; cette tendance se refliite dans l'importance relative des effets volumiques lors de la determination des frCquellces rilq de ces solides. On propose une thCorie simple pour expliquer la dependance entre la pression et les frkquences rnq des cristaux molCculaires; cette theorie tient compte de toutes les doililCes qui existent presentement. Ees coefficients de pression contiennent des contributions statiques et dynamiques qu.i son? de signes opposCs. La contribution statique est negative et devient numeriquement plus grande 2 mesure que la force de liaison intermolCculaii-e augmente.[Traduit par le journal]

show abstract

Low-Temperature In Situ Lithiation Construction of a Lithiophilic Particle-Selective Interlayer for Solid-State Lithium Metal Batteries

Zhao,

Luo,

et al. 2023

ACS Appl. Mater. Interfaces

View full text Add to dashboard Cite

Unexpected interface resistance and lithium dendrite puncture hinder the application of garnet-type solid-state electrolytes in high-energy-density systems. Different from the previous high-temperature (>180 °C) molten lithium that promotes the alloying reaction between the coating layer and Li to enhance the interface contact, herein, we introduce liquid-metal-like SbCl3 to construct a three-dimensional Li+ directional-selection interlayer by in situ low-temperature lithiation (80 °C). An interlayer with a more negative interface energy composed of SbLi3 and LiCl exhibits a superior affinity with Li and LGLZO, which reduces the interface resistance and suppresses the growth of Li dendrites by an insulated electron. The introduction of the SbCl3 modification layer into Li/Li symmetric cells enables charge/discharge at a current density of 6.0 mA cm–2 and operation for more than 1000 h under 2.0 mA cm–2 at room temperature. The full cells with the LiFePO4 cathode exhibit a high residual capacity of 144.8 mAh g–1 at 0.5 C after 1000 cycles and excellent cycling stability with a retention ratio of 94.7% at 1 C after 600 cycles. The low-temperature lithiation method based on an energy-saving perspective should be applied to other types of solid-state electrolyte modification strategies.

show abstract

The phase transitions near the melting point of sbCL3

Cited by 3 publications

References 4 publications

³⁵Cl Nuclear Quadrupole Relaxation in Antimony Trichloride

³⁵Cl Nuclear Quadrupole Relaxation in Antimony Trichloride

Nuclear quadrupole resonance and intermolecular interactions: temperature and pressure effects in Group V trichlorides

Low-Temperature In Situ Lithiation Construction of a Lithiophilic Particle-Selective Interlayer for Solid-State Lithium Metal Batteries

Contact Info

Product

Resources

About

The phase transitions near the melting point of sbCL3

Cited by 3 publications

References 4 publications

35Cl Nuclear Quadrupole Relaxation in Antimony Trichloride

35Cl Nuclear Quadrupole Relaxation in Antimony Trichloride

Nuclear quadrupole resonance and intermolecular interactions: temperature and pressure effects in Group V trichlorides

Low-Temperature In Situ Lithiation Construction of a Lithiophilic Particle-Selective Interlayer for Solid-State Lithium Metal Batteries

Contact Info

Product

Resources

About

³⁵Cl Nuclear Quadrupole Relaxation in Antimony Trichloride

³⁵Cl Nuclear Quadrupole Relaxation in Antimony Trichloride