The photoelectron spectra of some iron tricarbonyl complexes of 4π-electron donor ligands

Worley, S. D.; Webb, Thomas R.; Gibson, Dorothy H.; Ong, Tek-Sing

doi:10.1016/0368-2048(80)80046-6

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1996

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Cited by 17 publications

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“…The electronic absorption spectra of the radiolytically generated cations were measured in glassy matrices − and in solution . The ESR spectra of the radical cations were determined in low-temperature matrices. , The photoelectron spectra of trans - and cis -1,3-pentadiene and isoprene were recorded by various groups, − revealing the electronic states of the radical cations that are accessible by the removal of one electron from the neutral molecule. The gas phase photodissociation − and photoinduced dissociation 23,24 spectra were measured.…”

Section: Introductionmentioning

confidence: 99%

Radical Cations of Monomethyl-Substituted 1,3-Butadienes: Resonance Raman Spectra and Molecular Orbital Calculations

Keszthelyi

Wilbrandt

1996

J. Phys. Chem.

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The resonance Raman spectra of the trans-and cis-1,3-pentadiene and the 2-methyl-1,3-butadiene (isoprene) radical cations generated by γ-irradiation in a Freon glass are reported. The spectra are excited in resonance with the first absorption band. The spectra, which are interpreted with the help of density functional theory calculations, indicate the presence of both the s-trans and the s-cis rotamers of all three radical cations.

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