THE PHOTOSYNTHESIS OF SEMI-MUSTARD GAS, 2-CHLOROETHYL-2-HYDROXYETHYL SULFIDE<sup>1</sup>

Rueggeberg, Walter H. C.; Cook, Walter A.; Reid, E. Emmet

doi:10.1021/jo01159a014

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Hochzchzschzchzschzchzcl1

A Homolysis Of Disulfides1

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1952

2011

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Cited by 14 publications

(2 citation statements)

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“…The reaction with vinyl chloride is photochemically catalysed and is similar to that reported by Fuson and Zieglerz and Rueggeberg et aI. 4 for the preparation of HSM. EXPERIMENTAL METHODS 2(2'-Mercap toethy 1)mercaptoethanoE.…”

Section: Hochzchzschzchzschzchzclsupporting

confidence: 79%

The preparation, toxicity, and clinical evaluation of 1-(2-Chloroethylthio)-2(2-Hydroxyethylthio)Ethane (Hemisesquisulfur mustard)

Kramer¹,

Miller

Gaby

et al. 1957

Cancer

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Section: Hochzchzschzchzschzchzclsupporting

confidence: 79%

The preparation, toxicity, and clinical evaluation of 1-(2-Chloroethylthio)-2(2-Hydroxyethylthio)Ethane (Hemisesquisulfur mustard)

Kramer¹,

Miller

Gaby

et al. 1957

Cancer

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“…Light-induced homolysis of the sulfur-sulfur bond in dialkyl and diaryl disulfides gives thiyl radicals (87, 124,143,144). A quantum yield of unity was found by Whitney and Calvin (194) for the photolysis of 1,2-dithiolane and 6,8-thioctic acid.…”

Section: A Homolysis Of Disulfidesmentioning

confidence: 94%

The Scission Of The Sulfur-Sulfur Bond

Parker¹,

Kharasch²

1959

Chem. Rev.

327

152

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Formation of Carbon‐Hetero Atom Bonds by Free Radical Chain Additions to Carbon‐Carbon Multiple Bonds

Stacey

Harris

2011

Organic Reactions

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Free‐radical chain addition to carbon‐carbon multiple bonds to form carbon‐hetero atom bonds is an important synthetic method of wide scope. Carbon‐halogen, carbon‐sulfur, carbon‐silicon, carbon‐germanium, carbon‐phosphorus, and carbon‐nitrogen bonds have been formed by this method, In this chapter, the mechanism, scope, limitations, and experimental conditions are treated for the addition reactions that lead to the formation of the six types of carbon‐hetero atom bonds mentioned above. Since the direction of addition of free radicals to carbon‐carbon multiple bonds is common to all classes reviewed here, it is briefly explained.

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THE PHOTOSYNTHESIS OF SEMI-MUSTARD GAS, 2-CHLOROETHYL-2-HYDROXYETHYL SULFIDE¹

Cited by 14 publications

References 3 publications

The preparation, toxicity, and clinical evaluation of 1-(2-Chloroethylthio)-2(2-Hydroxyethylthio)Ethane (Hemisesquisulfur mustard)

The preparation, toxicity, and clinical evaluation of 1-(2-Chloroethylthio)-2(2-Hydroxyethylthio)Ethane (Hemisesquisulfur mustard)

The Scission Of The Sulfur-Sulfur Bond

Formation of Carbon‐Hetero Atom Bonds by Free Radical Chain Additions to Carbon‐Carbon Multiple Bonds

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THE PHOTOSYNTHESIS OF SEMI-MUSTARD GAS, 2-CHLOROETHYL-2-HYDROXYETHYL SULFIDE1

Cited by 14 publications

References 3 publications

The preparation, toxicity, and clinical evaluation of 1-(2-Chloroethylthio)-2(2-Hydroxyethylthio)Ethane (Hemisesquisulfur mustard)

The preparation, toxicity, and clinical evaluation of 1-(2-Chloroethylthio)-2(2-Hydroxyethylthio)Ethane (Hemisesquisulfur mustard)

The Scission Of The Sulfur-Sulfur Bond

Formation of Carbon‐Hetero Atom Bonds by Free Radical Chain Additions to Carbon‐Carbon Multiple Bonds

Contact Info

Product

Resources

About

THE PHOTOSYNTHESIS OF SEMI-MUSTARD GAS, 2-CHLOROETHYL-2-HYDROXYETHYL SULFIDE¹