The rapid desorption of gas in coal is an important cause of gas over-limit and outbursts. In order to explain the causes of coal and gas outbursts induced by vibration, this paper studies the gas desorption experiments of tectonic coal with different particle sizes and different adsorption equilibrium pressures under 0~50 Hz vibration. High-pressure mercury intrusion experiments were used to measure the changes in pore volume and specific surface area of tectonic coal before and after vibration, revealing the control of pore structure changes on the initial desorption capacity of gas. Additionally, from the perspective of energy transformation during coal and gas outbursts, the effect of vibration on the process of coal and gas outbursts in tectonic coal was analyzed. The results showed that tectonic coal has strong initial desorption capacity, desorbing 29.58% to 54.51% of the ultimate desorption volume within 10 min. Vibration with frequencies of 0~50 Hz increased both the gas desorption ratios and desorption volume as the frequency increased. The initial desorption rate also increased with the vibration frequency, and vibration can enhance the initial desorption capacity of tectonic coal and delay the attenuation of desorption rate. Vibration affected the changes in the initial gas desorption rate and desorption rate attenuation coefficient by increasing the pore volume and specific surface area, with the changes in macropores and mesopores primarily affecting the initial desorption rate and 0~10 min desorption ratios, while the changes in micropores and minipores mainly influenced the attenuation rate of the desorption rate. Vibration increased the free gas expansion energy of tectonic coal as the frequency increased. During the incubation and triggering processes of coal and gas outbursts, vibration has been observed to accelerate the fragmentation and destabilisation of the coal body, while simultaneously increasing the gas expansion energy to a point where it reaches the threshold energy necessary for coal transportation, thus inducing and triggering the coal and gas protrusion. The study results elucidate, from an energy perspective, the underlying mechanisms that facilitate the occurrence of coal and gas outbursts, providing theoretical guidance for coal and gas outburst prevention and mine safety production.