The post-synthesis modification (PSM) of MOFs for catalysis

Gadzikwa, Tendai; Matseketsa, Pricilla

doi:10.1039/d4dt00514g

Dalton Trans.

2024

DOI: 10.1039/d4dt00514g

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The post-synthesis modification (PSM) of MOFs for catalysis

Tendai Gadzikwa,

Pricilla Matseketsa

Abstract: While there are myriad ways to construct metal-organic framework (MOF) based catalysts, the introduction of catalytic functionality via covalent post-synthesis functionalization (PSM) offers multiple advantages: i) a wide range of...

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2024

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Cited by 5 publications

References 95 publications

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Post‐Synthetic Modification of a 1D Mixed‐Linker Zn(II) Coordination Polymer for Acid‐Catalyzed Alcoholysis of Epoxides

Najafi,

Janczak

2024

ChemPlusChem

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Rational design of heterogeneous acid catalysts possessing uniform dispersion of active sites plays a significant role in the catalytic performance. In the present work, a coordination polymer, [Zn(4,4'‐bpy)(μ‐Hbtc)(H2O)] ⋅ 2H2O (Zn‐CP), was solvothermally synthesized using 4,4'‐bpy (=4,4'‐bipyridine) and H3btc (=1,3,5‐benzenetricarboxylic acid) mixed linkers. Single crystal X‐ray analysis of the polymer displayed that Zn‐CP chains were decorated with 4,4'‐bpy having unidentate coordination fashion. Then, the free N atom of the linker in Zn‐CP was functionalized by ‐SO3H groups to afford Zn‐CP‐SO3H with enhanced acidity. The structures were characterized by FT‐IR, thermogravimetric analysis, powder X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS), temperature programmed desorption of NH3 (NH3‐TPD), and field emission scanning electron microscopy (FE‐SEM) analyses. The coordination polymer was employed as a heterogeneous catalyst for the alcoholysis of epoxides under room conditions. Zn‐CP‐SO3H exhibited excellent catalytic activity and regioselectivity in the methanolysis of styrene oxide within short reaction time.

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Post‐Synthetic Modification of a 1D Mixed‐Linker Zn(II) Coordination Polymer for Acid‐Catalyzed Alcoholysis of Epoxides

Najafi,

Janczak

2024

ChemPlusChem

View full text Add to dashboard Cite

show abstract

Applications of luminescent metal-organic frameworks as pioneering biosensors for biological and chemical detection

Fang,

Wang,

Ding

2024

Chinese Chemical Letters

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A comprehensive review on the enantiomeric separation of chiral drugs using metal-organic frameworks

Abbas,

Ahmad,

Cheng

et al. 2024

Chemosphere

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The post-synthesis modification (PSM) of MOFs for catalysis

Abstract: While there are myriad ways to construct metal-organic framework (MOF) based catalysts, the introduction of catalytic functionality via covalent post-synthesis functionalization (PSM) offers multiple advantages: i) a wide range of...

Cited by 5 publications

References 95 publications

Post‐Synthetic Modification of a 1D Mixed‐Linker Zn(II) Coordination Polymer for Acid‐Catalyzed Alcoholysis of Epoxides

Post‐Synthetic Modification of a 1D Mixed‐Linker Zn(II) Coordination Polymer for Acid‐Catalyzed Alcoholysis of Epoxides

Applications of luminescent metal-organic frameworks as pioneering biosensors for biological and chemical detection

A comprehensive review on the enantiomeric separation of chiral drugs using metal-organic frameworks

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