The Potential of Recycling Used Engine Oil for Biogas Generation by Co-Digestion with Animals’ Manure: Experimental and Kinetic Study

Abstract

This study investigates the potential of biogas recovery from used engine oil (UEO) by co-digestion with animals’ manure, including cow dung (CD), poultry manure (PM), and cattle manure (CM). The experimental work was carried out in anaerobic biodigesters at mesophilic conditions (37°C). Two groups of biodigesters were prepared. Each group consisted of 4 digesters. UEO was the main component in the first group of biodigesters with and without inoculum, whereby a mix of UEO and petroleum refinery oily sludge (ROS) was the component in the second group of biodigesters. The results revealed that for UEO-based biodigesters, maximum biogas production was 0.98, 1.23, 1.93, and 0 ml/g VS from UEO±CD, UEO±CM, UEO±PM, and UEO, respectively, whereby, for the UEO=ROS-based biodigesters, maximum biogas production was 3.49, 2.47, 3.64 and 2.44 ml/g VS from UEO+ROS±CD, UEO+ROS±CM, UEO+ROS±PM, and UEO+ROS, respectively. These results indicated that UEO was not feasible and efficient for biogas recovery since biogas production was very low in the first group of biodigesters compared to its recovery in the second group. A modified Gompertz model was applied to study the kinetics of the bio-digestion process. Measured and predicted values of biogas generation were fitted well with determination coefficients higher than 0.92.