The formation and evolution of hot subluminous B stars (sdB stars in the following) is not entirely understood. Although the current evolutionary status, i. e. the position in the Hertzsprung-Russell diagram, can be characterized and interpreted quite well, the preceding evolution of these objects remains uncertain. Since sdB stars do not follow a standard evolution of low mass stars, there must have been some event or phase in their history which led to a departure of the standard description. It is well-established in the literature that this event is connected to an enhanced mass loss of the sdB progenitor star during its red giant phase. This enhanced mass loss is a prerequisite to explain the very existence of sdB stars, its cause is, however, matter of debate. In the case of subdwarf B stars in binary systems, formation scenarios invoking Roche-lobe overflow and common envelope evolution are most promising. Theory and observations agree quite well in this case. However, there are some issues concerning single sdB stars, i. e. such stars which are not part of a binary system and therefore do not have a stellar companion. Such single sdB stars are an integral part of this thesis. One particular hypothesis discussed in the literature predicts that even substellar companions like brown dwarfs or exoplanets may be able to have a decisive influence on the formation of single sdB stars. A major goal of this present thesis is to investigate this hypothesis by searching for substellar companions to subdwarf B stars. Another goal is to pin down the evolutionary status of the investigated sdB stars and to directly measure their evolutionary timescales. The precise purposes are hence the search for substellar companions and the determination of evolutionary timescales. To achieve the goals mentioned above, the so-called EXOTIME program has been set up. EXOTIME conducts a long-term monitoring of five pulsating sdB stars with means of ground based time-resolved relative photometry. xi I will motivate the basic questions and intentions which led to the idea of setting up this thesis and to investigate the subdwarf B stars with respect to substellar companions. Chapter three is intended to introduce the purpose and goals of the EXOTIME project and to briefly characterize the target stars central to this thesis. Subsequently, in chapter four I will present the data archive built up during the last years, with a special emphasis on the observation facilities and observational strategy. Chapter five provides a description of the methods being applied to investigate the subdwarf B stars for substellar companions. A focus is set on the O-C timing method and a comparison to various other exoplanet detection methods. The results of the analysis are extensively presented in chapter six. Chapter seven will discuss these results, put them into a broader context and address various other implications and applications. A summary and outlook, as provided in chapter eight, will conclude this thesis. xiv -Miles Kington Welcome to Kington...