This article analyses the racial framing of the humanitarian encounter between Turkish and African Muslims as a trope of first contact. Intensifying humanitarian relations with Africa south of the Sahara, in tandem with the foreign policy of the AKP (Justice and Development Party), has led to the emergence of a racialized affective regime in Turkey that endows Islamic philanthropy with new racial meanings. This article argues that racial subjects such as the White Muslim and the Black Muslim are produced through the affective labour of humanitarian volunteers and others, who narrativize and circulate experiences of first contact in Turkey. Based on a multi-sited ethnography in Turkey, Tanzania, Senegal, Gambia and Benin, this article explores race-making as affective labour. Taking on Berg and Ramos-Zayas’s call for an anthropological theorization of race and affect, it develops a critical framework to examine how humanitarian voluntarism produces differently racialized subjects. In order to do so, this analysis draws on James Baldwin’s insights into the racial and affective politics of the first contact to discuss how Turkish humanitarians build on and alter the racialized affective regime Baldwin describes.